Cover of: N-Heterocyclic Carbenes in Transition Metal Catalysis | Frank Glorius Read Online
Share

N-Heterocyclic Carbenes in Transition Metal Catalysis by Frank Glorius

  • 138 Want to read
  • ·
  • 58 Currently reading

Published by Springer .
Written in English

Subjects:

  • Organometallic chemistry,
  • Science,
  • Science/Mathematics,
  • Chemistry - Clinical,
  • Chemistry - Inorganic,
  • Chemistry - Physical & Theoretical,
  • Catalysis,
  • Heterocyclic Chemistry,
  • Medicinal Chemistry,
  • Science / Chemistry / Inorganic

Book details:

Edition Notes

Topics in Organometallic Chemistry

The Physical Object
FormatHardcover
Number of Pages243
ID Numbers
Open LibraryOL9056742M
ISBN 103540369295
ISBN 109783540369295

Download N-Heterocyclic Carbenes in Transition Metal Catalysis

PDF EPUB FB2 MOBI RTF

Request PDF | On Jan 1, , F. A. Glorius and others published N-Heterocyclic Carbenes in Transition Metal Catalysis | Find, read and cite all the research you need on ResearchGateAuthor: Frank Glorius. Download n heterocyclic carbene catalysis or read online books in PDF, EPUB, Tuebl, and Mobi Format. Click Download or Read Online button to get n heterocyclic carbene catalysis book now. This site is like a library, Use search box in the widget to get ebook that you want. N . In this book leading experts have surveyed major areas of application of NHC metal complexes in catalysis. The authors have placed a special focus on nickel- and palladium-catalyzed reactions, on applications in metathesis reactions, on oxidation reactions and on the use of chiral NHC-based catalysts. Summarizing the emerging field of N-heterocyclic carbenes used in organocatalysis, this is an excellent overview of the synthesis and applications of NHCs focusing on carbon-carbon and carbon-heteroatom bond formation. His research focuses on the development of transition-metal-free carbon-carbon and carbon-heteroatom bond-forming reactions.

N‐Heterocyclic Carbenes. Editor(s): Steven P. Nolan; Edited by a leader and experienced scientist in the field of homogeneous catalysis and use of NHCs, this is an essential tool for every academic and industrial synthetic chemist. Reactivity, and Applications of Early Transition Metal Complexes Bearing N‐Heterocyclic Carbene. N-Heterocyclic carbenes are extensively used as coordinating ligands for the transition metal catalysis (1–6). On the other hand, silylenes are emerging as a novel class of versatile steering ligands in the coordination chemistry of the transition metals (TMs), and their complexes have demonstrated remarkable features in small-molecule. In less than 20 years N-heterocyclic carbenes (NHCs) have become well-established ancillary ligands for the preparation of transition metal-based catalysts. This is mainly due to the fact that NHCs tend to bind strongly to metal centres, avoiding the need of excess ligand in catalytic reactions. N-Heterocyclic Carbenes in Transition Metal Catalysis and Organocatalysis features all catalytic reactions enabled by N-heterocyclic carbenes (NHCs), either directly as organocatalysts or as ligands for transition metal catalysts. An explosion in the use of NHCs has been reported in the literature during the past seven years making this comprehensive overview highly : Springer Netherlands.

A persistent carbene (also known as stable carbene) is a type of carbene demonstrating particular stability. The best-known examples and by far largest subgroup are the N-heterocyclic carbenes (NHC) (sometimes called Arduengo carbenes), for example diaminocarbenes with the general formula (R 2 N) 2 C: where the 'R's are typically alkyl and aryl groups can be linked to give. In less than 20 years N-heterocyclic carbenes (NHCs) have become well-established ancillary ligands for the preparation of transition metal-based catalysts. This is mainly due to the fact that NHCs tend to bind strongly to metal centres, avoiding the need of excess ligand in catalytic reactions. Also, NHC‒metal complexes are often insensitive to air and moisture, and have proven remarkably. The use of N-heterocyclic carbenes (NHCs) in organic and transition metal chemistry is reviewed. This report presents the developments that have occurred in the last 12 months, describing the use of carbenes as ligands in transition metal chemistry and the catalytic uses of such transition metal complexes. Furthermore, NHCs can act as catalysts in their own right, and recent developments in. N-Heterocyclic Carbenes In Transition Metal Catalysis Frank Glorius It was only in the early s that carbenes with the carbene carbon being incorporated in a nitrogen containing heterocycle (N-heterocyclic carbenes or NHCs) were found to be stable enough to be isolated.